|
|
Electroplating |
|
Electroplating is the process for producing a metallic coating on a surface by electrodeposition - i.e.,
by the action of an electric current. Such coatings may perform a mainly protective function,
to prevent corrosion of the metal on which they are deposited: e.g.,
plating with zinc (electrogalvanizing) or with tin; or a decorative function: e.g.,
gold or silver-plating; or both functions; e.g., chromium plating.
|
|
The principle of electroplating is that the coating metal is deposited from an electrolyte-
an aqueous acid alkaline solution- on to the base: i.e., the metal to be coated (Fig.2). The
latter forms the cathode (negative electrode), while a plate of the metal to be deposited
serves as the anode (positive electrode). A low-voltage direct current is used; the anode
is gradually consumed. Additional agents are added to electroplating bath to obtain a
smooth and bright metal deposit. Sometimes the objects to be plated are coated with two
or more layers of different metals; for example, chromium plating cannot suitably be
applied directly to a zinc-sprayed base; a coating of copper followed by a coating
of nickel must be applied intermediately before the chromium is deposited.
|
|
For the achievement of good coating it is necessary to subject
the objects or components to a thorough cleaning. This may
be achieved by mechanical treatment e.g., sandblasting, grinding,
wire brushing, scraping, etc.; or by physical methods such
as degreasing with organic solvents; or by chemical methods
such as pickling with acid, or degreasing by the action of
alkalies (saponification); or by electrocleaning, which is
a method of cleaning by electrolytic action (more particularly
the scrubbing action exercised by the evolution of gas at
the surface of the metal). Wetting agents or emulsifiers may
be added. The vats for electroplating baths differ greatly
in size, shape and lining material (glass, lead, etc.), depending
on the size and shape of the components to be plated and on
the chemical character of the bath. Electroplating is normally
done with direct current. However, particularly with cyanide
copper baths, improved smoothness and uniformity of the coating
can be obtained by means of the so-called periodic-reverse
process, in which polarity is periodically reversed, so that
the metal is alternatively plated and depleted.
|
|
Steel strip is placed with zinc or with tin by continuous
and largely automated high-speed processes. The electrolytic
tin-plating process illustrated schematically in Fig.3 comprises
the following operations: electrolytic cleaning in dilute
sulphuric acid, pickling, electrodeposition of tin, melting
of the coating to give it a brilliant surface, chemical dipping
in chromate solutions, oiling, shearing. The steel strip travels
through the installation at a speed about 25m/min. (80ft./min).
A continuous zinc-plating installation is illustrated schematically
in Fig.4.
|
|
|
o DISCLAIMER
o CONTACT US |
|
|
|